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Earlier in his career, Guerrero feuded with Roddy Piper in California and Atsushi Onita in Japan over lighter-weight titles.

He usually teamed with his brothers, Mando and Hector wherever he wrestled. Prior to wrestling for World Wrestling Entertainment, his biggest exposure was in the late 1980s wrestling in the AWA on ESPN. He was teaming with his brother Mando to go after the AWA World Tag Team Championship held by Diamond Dallas Page's team of Badd Company (Paul Diamond and Pat Tanaka).

In 2004, Chavo Guerrero began working for WWE, joining his son Chavo Jr. in a feud with his brother Eddie.[1] While with WWE, where he competed as Chavo Classic, Guerrero had a brief reign as Cruiserweight Champion, which he would later lose to Rey Misteryo, becoming the oldest Cruiserweight Champion in history.[2] On June 15, 2004, he was fired by WWE for no-showing a SmackDown! house show two days earlier.[1]

On June 24, 2006 Punk made his ECW debut during a house show at the former ECW Arena, defeating Stevie Richards.[27] He made his TV debut on the July 4 episode of ECW on Sci Fi, cutting a brief pre-taped face promo about his straight edge lifestyle emphasizing the disciplinary aspects of being drug and alcohol free.[28] Although he had retained the straight edge gimmick, he now had a Muay Thai training background. Punk made his TV wrestling debut on August 1, 2006 at the Hammerstein Ballroom, defeating Justin Credible.[29] CM Punk established himself in ECW by going undefeated, defeating opponents such as Christopher W. Anderson,[30] Stevie Richards,[31] and Shannon Moore.[32]

Soon after, Punk began feuding with Mike Knox after Knox's girlfriend, Kelly Kelly, was seen to have feelings for Punk.[32] Punk defeated Mike Knox in their first singles match (qualifying for the Extreme Elimination Chamber at December to Dismember in the process)[33] as well as the rematch, after which Kelly Kelly celebrated CM Punk's victory over her boyfriend.[34] Punk then went on to team with D-Generation X and the Hardy Boyz in their Survivor Series match against Rated-RKO, Knox, Johnny Nitro and Gregory Helms, a match where all the participants on DX's side survived elimination.[35] At December to Dismember, Punk participated in the Extreme Elimination Chamber for the ECW World Championship, however he was the first person eliminated.[36]

CM Punk during ECW on Sci-Fi.Following this, Punk entered into a feud with Hardcore Holly, who ended Punk's six month unbeaten streak in singles competition on January 9, 2007.[37] Punk went on to feud with Matt Striker, who gave him his second singles loss since being in ECW on January 30.[38] Following this Punk qualified for the Money in the Bank ladder match at WrestleMania 23 by defeating Johnny Nitro,[39] being the only member of the ECW roster to qualify. In the final week leading up to WrestleMania 23 Punk made appearances on both RAW and SmackDown! defeating Kenny Dykstra[40] and former World Heavyweight Champion King Booker[41] respectively. At WrestleMania 23 Punk competed in, but did not win, the Money in the Bank ladder match being knocked off the ladder just seconds before the winner, Mr. Kennedy, claimed the briefcase.[42]

On the April 10 edition of ECW on Sci-Fi, Punk officially joined the New Breed stable,[43] after several weeks in which both the New Breed and the ECW Originals had attempted to recruit him.[44][45] However two weeks later Punk betrayed the New Breed during a four on four elimination match between the New Breed and ECW Originals by kicking New Breed leader Elijah Burke in the back of the head costing them the match. After the match Punk proceeded to deliver his finisher, the Go To Sleep, on Burke before leaving the ring alone. WWE.com later confirmed that Punk was no longer a member of the New Breed.[46] At Judgment Day 2007, Punk wrestled and defeated Elijah Burke in his first singles match on a pay-per-view.[47] Punk would then go on to One Night Stand 2007 and team up with Tommy Dreamer and The Sandman in a Tables match to defeat the New Breed.